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Vacancy filling effect of graphene on photoluminescence behavior of ZnO/graphene nanocomposite

Authors
Lee, EunsilKim, Jong-YoungKwon, Bob JinJang, Eue-SoonAn, Sung Jin
Issue Date
Oct-2014
Publisher
WILEY-V C H VERLAG GMBH
Keywords
graphene oxide; graphene; ZnO; photoluminescence; optoelectronic properties
Citation
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, v.8, no.10, pp.836 - 840
Journal Title
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS
Volume
8
Number
10
Start Page
836
End Page
840
URI
https://scholarworks.bwise.kr/kumoh/handle/2020.sw.kumoh/19181
DOI
10.1002/pssr.201409225
ISSN
1862-6254
Abstract
We report on the aerosol synthesis and optical characterization of ZnO/unoxidized graphene (UG) platelets nanocomposite films with high optical transparency (>85% at visible wavelengths). The ZnO/UG composite films, in which UG nanoplatelets are embedded in nano-grained ZnO, were fabricated from colloidal suspensions of UG platelets with an aqueous zinc precursor. From photoluminescence (PL) spectra of the UG composite films, it was found that PL intensity decreases with the addition of UG platelets. The features of PL intensity in the UG composites are in contrast to that of ZnO/graphene oxide (G-O) platelets composites, and can be explained by the absence of an oxygen vacancy filling effect, due to the unoxidized nature of UG and an increase in defect sites in its composites. ((c) 2014 WILEY-VCH Verlag GmbH &Co. KGaA, Weinheim)
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