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Visible-light-mediated photocatalytic difluoroalkylation/1,2-carbon migration sequences: synthesis of difluoroalkyl-substituted cyclic ketones
- Authors
- Suh, Chang Won; Kim, Dae Young
- Issue Date
- 7-Oct-2015
- Publisher
- Elsevier BV
- Keywords
- Difluoroalkylation; Photocatalysis; Radical reaction; 1,2-Carbon migration
- Citation
- Tetrahedron Letters, v.56, no.41, pp 5661 - 5664
- Pages
- 4
- Journal Title
- Tetrahedron Letters
- Volume
- 56
- Number
- 41
- Start Page
- 5661
- End Page
- 5664
- ISSN
- 0040-4039
- Abstract
- A visible-light-mediated photocatalytic ethoxycarbonyldifluoromethylation/1,2-carbon migration of alkenols is described. This approach provides a mild and operationally simple access to the synthesis of difluoralkyl-substituted cyclic ketones via difluoralkylation and 1,2-carbon migration of 1-(1-arylvinyl) cyclobutanol derivatives. (C) 2015 Published by Elsevier Ltd.
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)