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Catalytic asymmetric Mannich-type reactions of fluorinated ketoesters with N-Boc aldimines in the presence of chiral palladium complexes
- Authors
- Kang, Young Ku; Kim, Dae Young
- Issue Date
- 4-May-2011
- Publisher
- Elsevier BV
- Keywords
- Mannich reaction; Asymmetric catalysis; Chiral palladium catalysts; alpha-Fluoro-beta-ketoesters; Aldimines
- Citation
- Tetrahedron Letters, v.52, no.18, pp 2356 - 2358
- Pages
- 3
- Journal Title
- Tetrahedron Letters
- Volume
- 52
- Number
- 18
- Start Page
- 2356
- End Page
- 2358
- ISSN
- 0040-4039
- Abstract
- The catalytic enantioselective Mannich reaction promoted by chiral palladium complexes is described. The treatment of alpha-fluoro-beta-ketoesters with N-Boc-aldimines under mild reaction conditions afforded the corresponding beta-aminated alpha-fluoro-beta-ketoesters with excellent enantioselectivities (up to 99% ee). (C) 2011 Elsevier Ltd. All rights reserved.
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)