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Asymmetric Mannich-type Reactions of Fluorinated Ketoesters with Binaphthyl-Modified Thiourea Catalysts
- Authors
- Kang, Young Ku; Yoon, Sung Je; Kim, Dae Young
- Issue Date
- 20-Apr-2011
- Publisher
- 대한화학회
- Keywords
- Mannich reaction; Asymmetric catalysis; Bifunctional organocatalyst; alpha-Fluoro-beta-ketoesters; N-Boc imines
- Citation
- Bulletin of the Korean Chemical Society, v.32, no.4, pp 1195 - 1200
- Pages
- 6
- Journal Title
- Bulletin of the Korean Chemical Society
- Volume
- 32
- Number
- 4
- Start Page
- 1195
- End Page
- 1200
- ISSN
- 0253-2964
1229-5949
- Abstract
- The catalytic enantioselective Mannich-type reaction promoted by chiral binaphthyl-modified bifunctional organocatalysts is described. The treatment of alpha-fluoro-beta-ketoesters with N-Boc imines under mild reaction conditions afforded the corresponding beta-aminated alpha-fluoro-beta-ketoesters with excellent enantioselectivities (up to 98% ee).
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)