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Organocatalytic Enantioselective Mannich-Type Reactions of Fluorinated Keto Esters with N-Boc-Aldimines
- Authors
- Yoon, Sung Je; Kang, Young Ku; Kim, Dae Young
- Issue Date
- Feb-2011
- Publisher
- Georg Thieme Verlag
- Keywords
- Mannich reaction; asymmetric catalysis; bifunctional organocatalyst; alpha-fluoro-beta-keto esters; aldimines
- Citation
- Synlett, no.3, pp 420 - 424
- Pages
- 5
- Journal Title
- Synlett
- Number
- 3
- Start Page
- 420
- End Page
- 424
- ISSN
- 0936-5214
1437-2096
- Abstract
- The catalytic enantioselective Mannich reaction promoted by chiral bifunctional organocatalysts is described. The treatment of alpha-fluoro-beta-keto esters with N-Boc aldimines under mild reaction conditions afforded the corresponding beta-aminated alpha-fluoro-beta-keto esters with excellent enantioselectivities ( up to 98% ee).
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)