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Electrochemical trifluoromethylation/semipinacol rearrangement sequences of alkenyl alcohols: synthesis of beta-CF3-substituted ketones
- Authors
- Jung, Hye Im; Kim, Yubin; Kim, Dae Young
- Issue Date
- 7-Apr-2019
- Publisher
- Royal Society of Chemistry
- Keywords
- Electrochemistry; trifluoromethylation; semipinacol rearrangement; alkenyl alcohols; β-CF3-substituted ketones
- Citation
- Organic and Biomolecular Chemistry, v.17, no.13, pp 3319 - 3323
- Pages
- 5
- Journal Title
- Organic and Biomolecular Chemistry
- Volume
- 17
- Number
- 13
- Start Page
- 3319
- End Page
- 3323
- ISSN
- 1477-0520
1477-0539
- Abstract
- Electrochemical oxidative radical trifluoromethylation/ semipinacol rearrangement sequences of alkenyl alcohols were developed in this study. This approach is environmentally benign and uses the shelf-stable Langlois reagent as a trifluoromethyl radical precursor and electrons as the oxidizing reagents. The present protocol offers a facile route to prepare beta-trifluoromethylated ketone derivatives.
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)