Detailed Information
Cited 0 time in 
Cited 14 time in 
Cited 14 time in
Metadata Downloads
Organocatalytic asymmetric conjugate addition of 2-fluoro-1,3-diketones to nitroalkenes
- Authors
- Kim, Yubin; Kim, Yeon Joo; Jeong, Hye Im; Kim, Dae Young
- Issue Date
- Sep-2017
- Publisher
- Elsevier BV
- Keywords
- Organocatalysts; Asymmetric catalysis; Conjugate addition; 2-Fluoro-1,3-diketones
- Citation
- Journal of Fluorine Chemistry, v.201, pp 43 - 48
- Pages
- 6
- Journal Title
- Journal of Fluorine Chemistry
- Volume
- 201
- Start Page
- 43
- End Page
- 48
- ISSN
- 0022-1139
1873-3328
- Abstract
- The organocatalytic enantioselective conjugate reaction of 2-fluoro-1,3-diketones to nitroalkenes promoted by chiral binaphthyl-modified squaramide has been achieved. Treatment of 2-fluoro-1,3-diketones with nitroalkenes under mild reaction conditions afforded the corresponding Michael products containing fluorinated quaternary carbon stereocenter with excellent enantioselectivity (up to 98% ee).
- Files in This Item
- There are no files associated with this item.
- Appears in
Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)