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Growth behavior of artificial hexagonal GdMnO3 thin films

Authors
Lee, DaesuLee, Jung-HyukJang, Seung YupMurugavel, PattukkannuKo, Young-DongChung, Jin-Seok
Issue Date
15-Feb-2008
Publisher
ELSEVIER SCIENCE BV
Keywords
crystal structure; growth models; laser epitaxy; manganites; ferroelectric materials; magnetic materials
Citation
JOURNAL OF CRYSTAL GROWTH, v.310, no.4, pp.829 - 835
Journal Title
JOURNAL OF CRYSTAL GROWTH
Volume
310
Number
4
Start Page
829
End Page
835
URI
http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/16905
DOI
10.1016/j.jcrysgro.2007.11.101
ISSN
0022-0248
Abstract
The epitaxial growth of the artificial hexagonal GdMnO3 phase was investigated on substrates with hexagonal symmetries. The GdMnO3 thin films grown on Pt(1 1 1)/Al2O3(0 0 0 1) substrates showed a mixed state of a dominant hexagonal phase and small additional orthorhombic phases, which were stable in bulk. In this study, high oxygen partial pressures during film deposition were found to help to fabricate GdMnO3 thin films in the dominant hexagonal phase. Also, the growth behavior of the small additional orthorhombic GdMnO3 phases was studied by X-ray diffraction (XRD) measurements with a synchrotron radiation X-ray source. This study confirmed that even the orthorhombic GdMnO3 phases prefer specific orientations on the substrates with an in-plane hexagonal symmetry. (C) 2007 Elsevier B.V. All rights reserved.
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