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From Pincers to Steps: Synthesis, Structure, Characterization, and Transformation of a New Helical Calcium-Organic Framework, Ca[NC5H3(CO2)(2)](H2O)(1.5)
- Authors
- Kim, Min Kyung; Bae, Kyung-Lyul; Ok, Kang Min
- Issue Date
- Apr-2011
- Publisher
- AMER CHEMICAL SOC
- Citation
- CRYSTAL GROWTH & DESIGN, v.11, no.4, pp 930 - 932
- Pages
- 3
- Journal Title
- CRYSTAL GROWTH & DESIGN
- Volume
- 11
- Number
- 4
- Start Page
- 930
- End Page
- 932
- ISSN
- 1528-7483
1528-7505
- Abstract
- Unprecedented 1-D helical calcium organic framework material, Ca[NC5H3(CO2)(2)](H2O)(1.5), has been synthesized for the first time under hydrothermal reaction conditions using Ca(OH)(2), 2,6-NC5H3(CO2H)(2), (CH3)(2)-NCOH, HNO3, and H2O as reagents. A complete characterization including the transformation of the helical chain with pincers to another helix with steps by the reaction with water is reported.
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