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Nanoscale piezoresponse of 70 nm poly(vinylidene fluoride-trifluoro-ethylene) films annealed at different temperatures

Authors
Choi, Yoon-YoungHong, JonginHong, SeungbumSong, HanwookCheong, Deok-SooNo, Kwangsoo
Issue Date
Apr-2010
Publisher
WILEY-BLACKWELL
Keywords
atomic force microscopy; dielectrics; thin film; polymers
Citation
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, v.4, no.3-4, pp 94 - 96
Pages
3
Journal Title
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS
Volume
4
Number
3-4
Start Page
94
End Page
96
URI
https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/43717
DOI
10.1002/pssr.201004009
ISSN
1862-6254
1862-6270
Abstract
In order to characterize the piezoelectric properties of 70 nm thick poly(vinylidene fluoride-trifluoroethylene), P(VDF-TrFE), films grown by a spin-coating technique, both nanoscale manipulation and polarization switching were studied using piezoresponse force Microscopy (PFM). We varied the annealing, temperature from 75 degrees C to 145 degrees C and achieved a high-quality 70 nm P(VDF-TrFE) film annealed at the temperature of 95 degrees C. Ferroelecrtic domains and their properties were confirmed using X-ray diffraction, grazing incidence reflection absorption Fourier, Transform Infrared (GIRA-FTIR) and PFM analysis. The ferroelectric domains in the film were homogeneously switchable below 5 V with a remnant d(33) of 14.9 pm/V. This offers out rationale for a promise in energy harvesting and switchability would be good for plastic electronics. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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