Detailed Information
Cited 0 time in 
Cited 0 time in 
Cited 0 time in
Metadata Downloads
Bis(4,4''-difluoro-1,1':3',1''-terphenyl-2'-carboxylato-κO) tetrakis(methanol-κO)calcium methanol tetrasolvateopen access
- Authors
- Kim, Namseok; Noh, Heeso; Yoon, Sungho; Park, Chan Ryang
- Issue Date
- Feb-2013
- Keywords
- data-to-parameter ratio = 19.0; mean σ(C-C) = 0.004 Å; R factor = 0.064; single-crystal X-ray study; T = 200 K; wR factor = 0.165
- Citation
- Acta Crystallographica Section E: Structure Reports Online, v.69, no.2, pp m122 - m123
- Journal Title
- Acta Crystallographica Section E: Structure Reports Online
- Volume
- 69
- Number
- 2
- Start Page
- m122
- End Page
- m123
- ISSN
- 1600-5368
- Abstract
- In the title compound, [Ca(C19H11F2O 2)2(CH3OH)4]·4CH3OH, the Ca2+ ion is located on an inversion centre and is hexacoordinated by two O atoms of two 4,4''-difluoro-1,1':3',1''-terphenyl-2'-carboxylate ligands and four O atoms of four methanol ligands, forming a CaO6 polyhedron with a slightly distorted octahedral coordination geometry. The Ca - O - C angle between the carboxylate group and the calcium ion is 171.8 (2)°. Two types of intermolecular hydrogen-bond interactions (C=O⋯H and O - H⋯O) between the carboxylate ligand, the methanol solvent molecules and the coordinating methanol ligands generate a two-dimensional network parallel to (001).
- Files in This Item
- Appears in
Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.