Detailed Information
Cited 23 time in 
Cited 25 time in 
Cited 25 time in
Metadata Downloads
Synthesis of beta-Trifluoromethylated Ketones from Propargylic Alcohols by Visible Light Photoredox Catalysis
- Authors
- Park, Sehyun; Joo, Jung Min; Cho, Eun Jin
- Issue Date
- Jul-2015
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- Photocatalysis; Radical reactions; Trifluoromethylation; Propargylic alcohols; Ketones
- Citation
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2015, no.19, pp 4093 - 4097
- Pages
- 5
- Journal Title
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- Volume
- 2015
- Number
- 19
- Start Page
- 4093
- End Page
- 4097
- ISSN
- 1434-193X
1099-0690
- Abstract
- Regioselective trifluoromethylation at a remote position represents an important challenge in the development of biologically active molecules and functional materials. A practical method to access -trifluoromethyl ketones from readily available propargylic alcohols by visible light photocatalysis has been developed. Trifluoromethylation of propargylic alcohols with CF3I in the presence of Ru(bpy)(3)Cl-2 as the photocatalyst followed by double-bond migration/keto-enol tautomerization provides -trifluoromethyl ketones as the final product.
- Files in This Item
- There are no files associated with this item.
- Appears in
Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.