Ampere-hour-scale zinc–air pouch cells
- Authors
- Shinde, Sambhaji S.; Jung, Jin Young; Wagh, Nayantara K.; Lee, Chi Ho; Kim, Dong-Hyung; Kim, Sung-Hae; Lee, Sang Uck; Lee, Jung-Ho
- Issue Date
- Jun-2021
- Publisher
- NATURE PUBLISHING GROUP
- Citation
- Nature Energy, v.6, no.6, pp.592 - 604
- Indexed
- SCIE
SCOPUS
- Journal Title
- Nature Energy
- Volume
- 6
- Number
- 6
- Start Page
- 592
- End Page
- 604
- URI
- https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/113887
- DOI
- 10.1038/s41560-021-00807-8
- ISSN
- 2058-7546
- Abstract
- All-solid-state zinc–air pouch cells promise high energy-to-cost ratios with inherent safety; however, finding earth-abundant high power/energy cathodes and super-ionic electrolytes remains a fundamental challenge. Here we present realistic zinc–air pouch cells designed by the (101)-facet copper phosphosulfide [CPS(101)] as a cathode as well as anti-freezing chitosan-biocellulosics as super-ionic conductor electrolytes. The proposed CPS(101) exhibits trifunctional activity and stability (>30,000 cycles) towards reversible oxygen reactions and hydrogen evolution reactions, outperforming commercial Pt/C and RuO2. Furthermore, hydroxide super-ion conductors utilizing polymerized chitosan-biocellulosics reveal exceptional conductivity (86.7 mS cm−1 at 25 °C) with high mechanical/chemical robustness. High cell-level energy densities of 460 Wh kgcell–1/1,389 Wh l−1 are normally measured in pouch cells (1 Ah) with a cycle lifespan of 6,000/1,100 cycles at 25 mA cm−2 for 20/70% depths of discharge, and the highest densities we could achieve were 523 Wh kgcell–1/1,609 Wh l−1. Flexible pouch cells operate well at rates of 5–200 mA cm−2 over a broad temperature range of −20 to 80 °C. © 2021, The Author(s), under exclusive licence to Springer Nature Limited.
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Collections - COLLEGE OF ENGINEERING SCIENCES > DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING > 1. Journal Articles
- COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY > DEPARTMENT OF CHEMICAL AND MOLECULAR ENGINEERING > 1. Journal Articles
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