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Area-Selective Atomic Layer Deposition of Ruthenium Thin Films by Chemo-Selective Adsorption of Short Alkylating Agents

Authors
Lee,Jeong-MinKim, Woo-Hee
Issue Date
May-2023
Publisher
Institute of Electrical and Electronics Engineers Inc.
Keywords
Aminosilane inhibitor; Area-selective atomic layer deposition; Ruthenium; Surface modification
Citation
2023 IEEE International Interconnect Technology Conference and IEEE Materials for Advanced Metallization Conference, IITC/MAM 2023 - Proceedings, pp.1 - 3
Indexed
SCOPUS
Journal Title
2023 IEEE International Interconnect Technology Conference and IEEE Materials for Advanced Metallization Conference, IITC/MAM 2023 - Proceedings
Start Page
1
End Page
3
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/114240
DOI
10.1109/IITC/MAM57687.2023.10154801
ISSN
2380-632X
Abstract
As advanced semiconductor devices went into the extremely narrow dimensions, ruthenium has received great deal of attention for next-generation gate electrodes and metal interconnects. Accordingly, area-selective atomic layer deposition (AS-ALD) of Ru films is essentially required. In this work, we report effects of surface modification treated with vapor dosing of (N,N-diethylamino)trimethylsilane (DEATMS) as small alkylating agents on technologically important substrates of Si, SiO2, SiN, TiN, and W against Ru ALD. Through enhanced adsorption of DEATMS with discrete feeding method (DFM), significant growth retardation against Ru ALD was selectively found on SiO2, SiN, and TiN in contrast to Si-H and W. © 2023 IEEE.
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Kim, Woo Hee
ERICA 공학대학 (DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING)
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