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The Impact of Carbon Concentration on the Crystalline Phase and Dielectric Constant of Atomic Layer Deposited HfO2 Films on Ge Substrate

Authors
Jung, Hyung-SukJeon, Sang HoKim, Hyo KyeomYu, Il-HyukLee, Sang YoungLee, JoohwiChung, Yoon JangCho, Deok-YongLee, Nae-InPark, Tae JooChoi, Jung-HaeHan, SeungwuHwang, Cheol Seong
Issue Date
Jul-2012
Publisher
Electrochemical Society, Inc.
Citation
ECS Journal of Solid State Science and Technology, v.1, no.2, pp.N33 - N37
Indexed
SCIE
SCOPUS
Journal Title
ECS Journal of Solid State Science and Technology
Volume
1
Number
2
Start Page
N33
End Page
N37
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/36274
DOI
10.1149/2.020202jss
ISSN
2162-8769
Abstract
The effect of the carbon concentration on the crystalline phase and dielectric constant (k) of atomic layer deposited HfO2 films on Ge substrate was investigated. After annealing, the HfO2 films grown at 200 degrees C and 280 degrees C were crystallized to the tetragonal (t) and monoclinic (m) phases, respectively, which was related to the carbon contents within the films and grain boundary energy. To clarify this, the energy difference between a t- and a m-phases (Delta E-tetra) was calculated by first principles calculations. The higher k value of t-HfO2 compared to amorphous and monoclinic HfO2 was experimentally confirmed. (C) 2012 The Electrochemical Society. All rights reserved.
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Park, Tae Joo
ERICA 공학대학 (DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING)
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