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Corrosion resistance of oxide layers formed on AZ91 Mg alloy in KMnO4 electrolyte by plasma electrolytic oxidation

Authors
Hwang, Duck YoungKim, Yong MinPark, Deok-YongYoo, BongyoungShin, Dong Hyuk
Issue Date
Sep-2009
Publisher
Pergamon Press Ltd.
Keywords
Magnesium alloy; Plasma electrolytic oxidation; Corrosion; Potassium permanganate; Anodizing
Citation
Electrochimica Acta, v.54, no.23, pp 5479 - 5485
Pages
7
Indexed
SCIE
SCOPUS
Journal Title
Electrochimica Acta
Volume
54
Number
23
Start Page
5479
End Page
5485
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/40872
DOI
10.1016/j.electacta.2009.04.047
ISSN
0013-4686
1873-3859
Abstract
The plasma electrolytic oxidation (PEO) process in AZ91 Mg alloy is studied using a solution containing KOH + KF + Na2SiO3 both with and without potassium permanganate (KMnO4). The addition of potassium permanganate to the electrolyte influences coating thickness, surface morphology and the microstructure of oxide layers obtained by the PEO process. Oxide layers formed on AZ91 Mg alloy by the electrolyte containing KMnO4 consists of MgO, MgF2, Mg2SiO4 and Mn2O3. The corrosion resistance of the sample processed in bath containing KMnO4 was superior to that of the sample processed in the bath without KMnO4. It is suggested that enhancement of the corrosion resistance of AZ91 Mg alloy depends strongly on the presence of manganese oxide in the oxide layer. (C) 2009 Elsevier Ltd. All rights reserved.
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ERICA 첨단융합대학 (ERICA 신소재·반도체공학전공)
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