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Effect of sodium periodate in alumina-based slurry on RuCMP for metal-insulator-metal capacitor

Authors
Kim, In-KwonKang, Young-JaeKwon, Tae-YoungCho, Byoung-GwunPark, Jin-GooPark, Jum-YongPark, Hyung-Soon
Issue Date
Apr-2008
Publisher
Electrochemical Society, Inc.
Citation
Electrochemical and Solid-State Letters, v.11, no.6, pp.H150 - H153
Indexed
SCIE
SCOPUS
Journal Title
Electrochemical and Solid-State Letters
Volume
11
Number
6
Start Page
H150
End Page
H153
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/43115
DOI
10.1149/1.2901544
ISSN
1099-0062
Abstract
In this study, a ruthenium (Ru) chemical mechanical planarization (CMP) slurry was developed and characterized to fabricate Ru bottom electrodes in capacitor structures. Sodium periodate (NaIO(4)) was chosen as both the oxidant and etchant due to its strong oxidizing power. The effect of NaIO(4) on Ru etching and polishing behaviors was investigated as a function of its concentration and polishing condition. The largest removal rate of 70 nm/min was obtained in a slurry of 0.1 M NaIO(4) and 2 wt % alumina particles at pH 9 and a polishing pressure of 4 psi. Planarization and isolation of each capacitor was successfully performed with the developed Ru slurry.
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ERICA 공학대학 (DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING)
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