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Development of post Ru CMP cleaning solutions

Authors
Kim, In-KwonCho, Byung-GwunKim, Tae GonPark, Jin-Goo
Issue Date
Oct-2007
Publisher
VDE Verlag GmbH
Keywords
Chemical mechanical planarization (CMP); Particle removal efficiency (PRE); Post CMP cleaning; Ruthenium (Ru)
Citation
ICPT 2007 - International Conference on Planarization/CMP Technology, Proceedings, pp.283 - 287
Indexed
SCOPUS
Journal Title
ICPT 2007 - International Conference on Planarization/CMP Technology, Proceedings
Start Page
283
End Page
287
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/44240
Abstract
Ru (ruthenium) has been suggested as an electrode in DRAM and a Cu diffusion barrier metal for Cu interconnection. To planarize deposited Ru layer, chemical mechanical planarization (CMP) was suggested. However, abrasive particles can be easily contaminated on the Ru surface after polishing. In this study, zeta potentials of abrasive particle were measured as a function of pH. The etch rate and oxidation behavior of Ru were observed as a function of concentration of various acidic and alkaline chemicals. PRE (particle removal efficiency) was also evaluated in different cleaning solutions. Zeta potentials of abrasive particle decreased as a function of pH in these chemicals. Ru layer was etched and oxidized in a selected chemical. The highest particle removal efficiency was observed in a solution with citric acid at pH 9. © ICPT 2007 - International Conference on Planarization/CMP Technology, Proceedings. All rights reserved.
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COLLEGE OF ENGINEERING SCIENCES > DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING > 1. Journal Articles
COLLEGE OF ENGINEERING SCIENCES > MAJOR IN APPLIED MATERIAL & COMPONENTS > 1. Journal Articles

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Park, Jin Goo
ERICA 공학대학 (DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING)
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