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Synthesis and thermoelectric characterization of bulk-type tellurium nanowire/polymer nanocomposites

Authors
Kim, SeilLee, Young-InRyu, Seung HanHwang, Tae-YeonSong, YosebSeo, SunghoYoo, BongyoungLim, Jae-HongCho, Hong-BaekMyung, Nosang V.Choa, Yong-Ho
Issue Date
Nov-2017
Publisher
Kluwer Academic Publishers
Citation
Journal of Materials Science, v.52, no.21, pp 12724 - 12733
Pages
10
Indexed
SCI
SCIE
SCOPUS
Journal Title
Journal of Materials Science
Volume
52
Number
21
Start Page
12724
End Page
12733
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/8531
DOI
10.1007/s10853-017-1384-z
ISSN
0022-2461
1573-4803
Abstract
A simple method to fabricate three-dimensionally (3-D) aligned thermoelectric nanowires attached polymer particle was demonstrated by combination of solution casting of thermoelectric nanostructures (e.g., tellurium nanowires (Te NWs)) on the surface of thermoplastic polymer (e.g., poly(methyl methacrylate (PMMA)) microbeads followed by hot compaction of thermoplastic matrix. The percolation threshold of composite with 3-D assembled Te NWs (i.e., 3.45 vol%) significantly was lower than that of a randomly dispersed Te NWs (i.e., 5.26 vol%), which resulted in an order of magnitude greater thermoelectric figure of merit (ZT of 2.8 x 10(-3)) compared to randomly dispersed Te NWs in PMMA matrix (ZT of 6.4 x 10(-4)) at room temperature by enhancing the electrical conductivity without increasing thermal conductivity.
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ERICA 첨단융합대학 (ERICA 신소재·반도체공학전공)
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