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고밀도 플라즈마를 이용한 SnO2 박막의 건식 식각 특성A Study on Etching Characteristics of SnO2 Thin Films Using High Density Plasma

Authors
김환준주영희김승한우종창김창일
Issue Date
2013
Publisher
한국전기전자재료학회
Keywords
SnO2; Etching; Inductively coupled plasma; BCl3; XPS
Citation
전기전자재료학회논문지, v.26, no.11, pp 826 - 830
Pages
5
Journal Title
전기전자재료학회논문지
Volume
26
Number
11
Start Page
826
End Page
830
URI
https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/19415
DOI
10.4313/JKEM.2013.26.11.826
ISSN
1226-7945
Abstract
본 연구에서는 유도 결합 플라즈마 식각 장비를 사용하여 SnO2 박막의 식각 특성과 공정에 대하여 연구하였다. O2/BCl3/Ar의 식각 가스 혼합비를 변화시켜 SnO2 박막의 식각 실험을 진행하였다. 기본 공정 조건은 700 W의 RF 전력, - 150 V의 직류 바이어스 전압, 2 Pa의 공정 압력으로 고정하였다. 실험 결과 O2/BCl3/Ar=(3:4:16 sccm) 플라즈마에서 최대 식각 속도인 509.9 nm/min을 얻었다. XPS 분석을 통하여 O2/BCl3/Ar 플라즈마에서의 SnO2 박막의 식각 메커니즘을 알아보았다. 또한 식각 후 박막의 표면 상태와 단면 현상은 각각 AFM과 FE-SEM을 통하여 알아보았다.
In this paper, we carried out the investigations of both etch characteristics and mechanisms for the SnO2 thin films in O2/BCl3/Ar plasma. The dry etching characteristics of the SnO2 thin films was studied by varying the O2/BCl3/Ar gas mixing ratio. We determined the optimized process conditions that were as follows: a RF power of 700 W, a DC-bias voltage of – 150 V, and a process pressure of 2 Pa. The maximum etch rate was 509.9 nm/min in O2/BCl3/Ar=(3:4:16 sccm) plasma. From XPS analysis, the etch mechanism of the SnO2 thin films in the O2/BCl3/Ar plasma can be identified as the ion-assisted chemical reaction while the role of ion bombardment includes the destruction of the metal-oxide bonds as well as the cleaning of the etched surface form the reaction products.
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